It's a very polarizing choice that would require different playstyles involved. Consider them being mostly in a flier team.
Narcian has the advantage of being able to easily bait and tank Reinhardt as well as virtually any blue unit. Which makes him a great frontliner in these blue dominated matches. His disadvantage is that he excels only at this and has mediocre results against greens and dies to reds. His team would have to probably compensate for it by running two blues.
Cherche (with brave axe) can only tank physical dmg and should never get attacked by mages (a problem in a mage dominated meta), so she requires movement support skill abuse and an escape mechanism. Her damage output (even without flier buffs) is impressive tho and she easily kills most of the heroes she initiates upon.
Choosing one of them for a primary flier team is actually quite a dilemma. I know it's a very subjective question and it depends largely on every person's playstyle, but which one of them do you find better in a flier team?