It'll give you 1 or 2 more matches per week at best, depending on how well you collect Aether during your matches. This doesn't make any real difference until you're up in the higher tiers (19 and above).
If you lose heroes often in AR offense, or if it happens that you lose matches, then you probably won't go farther than tier 19 and in this case I don't recommend upgrading the pots as you won't need the extra matches. Now if you think you are a skilled player AND that your defense is okay (average of -60 or -40) then the 2 matches provided by the pots could make you climb tiers if you don't have an optimal scoring using Eir and blessings (though you should at least score 120 per match to hope getting higher).
TL;DR If you are a top player and win consistently, upgrade them; otherwise don't.
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